Estimation of the Shape Factor of Aggregates in Self-Associating Systems Based on Metallosurfactants

— A mathematical evaluation of the shape factor of aggregates formed by amphiphilic compounds in an aqueous medium has been carried out on the basis of dynamic light scattering data for self-associating systems based on metallocomplexes of alkylated derivatives of 1,4-diazabicyclo[2.2.2]octane with...

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Veröffentlicht in:Colloid journal of the Russian Academy of Sciences 2023-06, Vol.85 (3), p.358-365
Hauptverfasser: Zhil’tsova, E. P., Islamov, D. R., Zakharova, L. Ya
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Sprache:eng
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Zusammenfassung:— A mathematical evaluation of the shape factor of aggregates formed by amphiphilic compounds in an aqueous medium has been carried out on the basis of dynamic light scattering data for self-associating systems based on metallocomplexes of alkylated derivatives of 1,4-diazabicyclo[2.2.2]octane with Ag(I) and Gd(III) nitrates, a ligand, and a ligand–inorganic salt mixture. Micellar and vesicular approximations have been used. A relationship between the shape factor and the parameters of the water pool of an aggregate has been shown for vesicular systems.
ISSN:1061-933X
1608-3067
DOI:10.1134/S1061933X23600252