Solubility in Ternary System NdCl3–PrCl3–H2O at 25°С

Solubility in Ternary System NdCl3–PrCl3–H2O at 25°С

The solubility diagram of the ternary system NdCl 3 –PrCl 3 –H 2 O has been studied by the method of isothermal saturation in ampules at 25°C. In the system NdCl 3 –PrCl 3 –H 2 O, isovalent substitution solid solutions with the miscibility gap (PrCl 3 ) x (NdCl 3 ) 1 – x ·6H 2 O and (PrCl 3 ) x (NdC...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian Journal of Physical Chemistry A 2023-08, Vol.97 (8), p.1685-1691
Hauptverfasser: Rumyantsev, A. V., Gur’eva, A. A., German, V. P., Keskinov, V. A., Charykov, N. A., Blokhin, A. A., Kulenova, N. A., Shaimardanova, B. K., Sadenova, M. A., Shushkevich, L. V.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Crystallization
Miscibility
Physical Chemistry
Physical Chemistry of Solutions
Solid phases
Solid solutions
Solubility
Ternary systems
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The solubility diagram of the ternary system NdCl 3 –PrCl 3 –H 2 O has been studied by the method of isothermal saturation in ampules at 25°C. In the system NdCl 3 –PrCl 3 –H 2 O, isovalent substitution solid solutions with the miscibility gap (PrCl 3 ) x (NdCl 3 ) 1 – x ·6H 2 O and (PrCl 3 ) x (NdCl 3 ) 1 – x ·7H 2 O have been crystallized. In the system, there is one non-invariant eutonic type point, corresponding to the saturation of the solution by two solid phases .
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024423080228