Structural, Spectroscopic and Molecular Characterization of an Asymmetric Schiff Base Compound

Structural, Spectroscopic and Molecular Characterization of an Asymmetric Schiff Base Compound

2-((E)-((2-(((E)-2-hydroxy-3-methylbenzylidene)amino)benzyl)imino)methyl)-6-methylphenol, C 23 H 22 N 2 O 2 , was synthesized by the reaction between 2-hydroxy-3-methylbenzaldehyde, and 2-(aminomethyl)aniline in aqueous ethanol. X-ray diffraction analysis technique was used to reveal the structure....

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Veröffentlicht in:Journal of structural chemistry 2023-06, Vol.64 (6), p.1147-1163
Hauptverfasser: Doğan, O. E., Poyraz, E. B., Saraçoğlu, H., Ağar, T., Yaşa, B., Dege, N.
Format: Artikel
Sprache:eng
Schlagworte:
Aniline
Atomic
Atomic/Molecular Structure and Spectra
Chemical synthesis
Chemistry
Chemistry and Materials Science
Crystal structure
Ethanol
Fourier transforms
Hydrogen bonds
Imines
Infrared spectra
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Structural analysis
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Beschreibung
Zusammenfassung:2-((E)-((2-(((E)-2-hydroxy-3-methylbenzylidene)amino)benzyl)imino)methyl)-6-methylphenol, C 23 H 22 N 2 O 2 , was synthesized by the reaction between 2-hydroxy-3-methylbenzaldehyde, and 2-(aminomethyl)aniline in aqueous ethanol. X-ray diffraction analysis technique was used to reveal the structure. The crystal structure is monoclinic, space group P 2 1 / c with parameters a  = 4.6035(11) Å, b  = 18.895(3) Å, c  = 21.748(6) Å, β = 100.23(4)°, V  = 1794(16) Å 3 , Z  = 4. It was determined by the Hirshfeld surface study that intermolecular hydrogen bonds stabilized the complex structure. Structure verified by Fourier transform infrared spectra technique.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476623060161