A Boronate Ester Driven Rechargeable Antibacterial Membrane for Fast Molecular Sieving

Membrane decorated with biocides is an effective way to suppress biofilm growth. However, their immediate biocidal effect usually suffers from a significant decline due to the irreversible consumption of the biocides. Here, a smart nanofiltration membrane is reported with rechargeable antibacterial capability that is fabricated by a facile interfacial polymerization via 3‐aminophenylboronic acid and trimesoyl chloride on a polysulfone substrate. Biocides bearing diol groups can be grafted onto the membrane surface under neutral/alkaline condition and then released from the surface under acidic environment, due to the pH‐responsive feature of boronate ester complexes. The resultant membrane exhibits integrated properties of fast bacterial inactivating efficiency, rechargeable antibacterial capability, and impressive stability. In addition, the achieved membrane shows remarkable separation efficiency to dye/monovalent salt system. The successful fabrication of the membrane with rechargeable anti‐bacterial property provides new insights into the development of pH‐responsive and sustainable antibacterial membranes. A boronic acid‐based smart nanofiltration membrane with rechargeable antibacterial capability is developed. The boronic acid‐rich surface enables the membrane to be armored with diol‐bearing bactericides via boronate ester complexes under natural/alkaline condition. By pH stimuli, exhausted bactericides are released, regenerating a clean surface to be available for next cycle recharging with fresh bactericides.