Acid-Catalyzed Acetonation of D-Ribose

Acid-Catalyzed Acetonation of D-Ribose

With the goal of identifying by-products in the cyanation of an imidate donor with trimethylsilyl cyanide, the main compounds formed in the sulfuric acid-, p -toluenesulfonic acid-, camphor-10-sulfonic acid-, and pyridinium p -toluenesulfonate-catalyzed acetonation of D-ribose were isolated and char...

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Veröffentlicht in:Russian journal of organic chemistry 2023-04, Vol.59 (4), p.581-590
Hauptverfasser: Valiullina, Z. R., Ivanova, N. A., Shavaleeva, G. A., Akhmetdinova, N. P., Lobov, A. N., Abdullin, M. F., Miftakhov, M. S.
Format: Artikel
Sprache:eng
Schlagworte:
Camphor
Chemistry
Chemistry and Materials Science
Mass spectrometry
NMR
Nuclear magnetic resonance
Organic Chemistry
Ribose
Spectral methods
Sulfonic acid
Sulfuric acid
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Beschreibung
Zusammenfassung:With the goal of identifying by-products in the cyanation of an imidate donor with trimethylsilyl cyanide, the main compounds formed in the sulfuric acid-, p -toluenesulfonic acid-, camphor-10-sulfonic acid-, and pyridinium p -toluenesulfonate-catalyzed acetonation of D-ribose were isolated and characterized by spectral methods, including 2D NMR techniques and high-resolution mass spectrometry.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428023040048