Synthesis and Characterization of Nylon 6,6-Polyvinyl Alcohol-Based Polyelectrolytic Membrane

This work presents the preparation and investigation of blended nylon (N)/polyvinyl alcohol (PVA)-based polyelectrolytic membranes that are modified with different concentrations of sulfuric acid (SA), chlorosulfonic acid (CSA), and sulfonated activated carbon (SAC) as a filler. Scanning electron microscopy (SEM) micrographs illustrated good membrane homogeneity, and no cracks or phase separation were detected. Chemical interaction between N, PVA, and other membrane components was confirmed by Raman scattering spectroscopy and Fourier transform infrared (FTIR). In addition, the molecular structure is verified by energy depressive X-ray (EDX). Furthermore, water and methanol uptake, gel fraction, and IEC were determined as functions of varied membrane modification components. The results revealed that increasing the portion of SA, CSA and SAC led to an increase in IEC and ionic conductivity values reached 2.12 meq/g–0.076 S/cm for (N/PVA-4.0% SA-4.0% SAC), respectively, and 2.71 meq/g–0.087 S/cm for (N/PVA-4.0% CSA-4.0% SAC), respectively, while the IEC and ionic conductivity value for non-modified N/PVA membrane was 0.02 meq/g and zero, respectively. Such results enhance the potential feasibility of modified N/PVA electrolytic membranes for fuel cell (FC) applications.