Titelbild: Chiral Supramolecular Multiblock Copolymerization Accompanying Chirality Transfer in Heterostructures via Living Chain Growth (Angew. Chem. 25/2023)

The copolymerization of kinetically trapped states of tetraphenylethylene containing glycine (TPE‐G) and/or D‐/L‐alanine moieties leads to the formation of supramolecular multi‐block copolymers, such as B‐A‐B, A‐B‐A‐B‐A, and C‐B‐A‐B‐C patterns (BCPs; tri‐ and penta‐blocks) by a chain‐growth process. The chirality of the supramolecular BCPs was not only successfully controlled by the chiral seed, but it also transferred to an achiral component during the chain‐growth polymerization, as reported Sung Ho Jung, Jong Hwa Jung et al. in their Research Article (e202300913).