Synthesis, Structure, and Properties of Copper(II) Complexes with 2,5-Bis(Ethylthio)-1,3,4-Thiadiazole

Structures of two new copper(II) chloride complexes with 2,5-bis(ethylthio)-1,3,4-thiadiazole (L), mononuclear CuL 2 Cl 2 and tetranuclear Cu 4 L 4 Cl 8 , are determined by X-RAY diffractometry. The polycrystalline phase of the CuL 2 Cl 2 complex is determined and studied by CHN analysis, IR spectro...

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Veröffentlicht in:	Journal of structural chemistry 2023-05, Vol.64 (5), p.895-905
Hauptverfasser:	Lavrenova, L. G., Komarov, V. Yu, Glinskaya, L. A., Lavrov, A. N., Artem′ev, A. V.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Copper chloride Infrared spectroscopy Inorganic Chemistry Magnetic permeability Molecular Optical and Plasma Physics Physical Chemistry Solid State Physics Thiadiazoles
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Zusammenfassung:	Structures of two new copper(II) chloride complexes with 2,5-bis(ethylthio)-1,3,4-thiadiazole (L), mononuclear CuL 2 Cl 2 and tetranuclear Cu 4 L 4 Cl 8 , are determined by X-RAY diffractometry. The polycrystalline phase of the CuL 2 Cl 2 complex is determined and studied by CHN analysis, IR spectroscopy, powder XRD, and static magnetic susceptibility methods.
ISSN:	0022-4766 1573-8779
DOI:	10.1134/S0022476623050086