New o-benzoquinones substituted with tert-octyl groups

A series of o -benzoquinones containing 2,4,4-trimethyl-2-pentyl ( tert -octyl) substituents were synthesized. The stability of the reduced forms of the synthesized o -quinones and the electron density distribution in the corresponding radical anion species were studied by cyclic voltammetry and EPR...

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Veröffentlicht in:Russian chemical bulletin 2023-05, Vol.72 (5), p.1192-1202
Hauptverfasser: Kocherova, T. N., Druzhkov, N. O., Arsenyev, M. V., Baranov, E. V., Kuropatov, V. A., Cherkasov, V. K.
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Sprache:eng
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Zusammenfassung:A series of o -benzoquinones containing 2,4,4-trimethyl-2-pentyl ( tert -octyl) substituents were synthesized. The stability of the reduced forms of the synthesized o -quinones and the electron density distribution in the corresponding radical anion species were studied by cyclic voltammetry and EPR spectroscopy.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-023-3889-8