Behavior of selenium and arsenic in HCl and HNO3 on TRU, TEVA, DGA, and Pb extraction chromatography resins

The uptake behavior of 73 As and 75 Se was studied in HCl and HNO 3 -H 2 O 2 solutions on commercial extraction chromatography resins (TEVA, TRU, DGA, and Pb resin). There was no uptake of 73 As or 75 Se from HNO 3 media. From HCl, there was 75 Se uptake at high concentrations on all the resins and...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2023-06, Vol.332 (6), p.1647-1655
Hauptverfasser: Kmak, Kelly N., Despotopulos, John D., Scielzo, Nicholas D.
Format: Artikel
Sprache:eng
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Zusammenfassung:The uptake behavior of 73 As and 75 Se was studied in HCl and HNO 3 -H 2 O 2 solutions on commercial extraction chromatography resins (TEVA, TRU, DGA, and Pb resin). There was no uptake of 73 As or 75 Se from HNO 3 media. From HCl, there was 75 Se uptake at high concentrations on all the resins and no uptake of 73 As. Separations of 75 Se and 73 As on these resins have high yields and high radiopurity for 73 As, but limited recovery of 75 Se. TRU and TEVA resin may have potential for use in isotope generators as 75 Se can be retained for at least 26 days with repeated elutions.
ISSN:0236-5731
1588-2780
DOI:10.1007/s10967-023-08904-6