Innentitelbild: Modular Synthesis of a Tridecasaccharide Motif of Bacteroides vulgatus Lipopolysaccharides against Inflammatory Bowel Diseases through an Orthogonal One‐Pot Glycosylation Strategy (Angew. Chem. 22/2023)

Lipopolysaccharides from Bacteroides vulgatus represent interesting targets for the treatment of inflammatory bowel diseases. In their Research Article (e202301351), Guozhi Xiao and co‐workers accomplished the first synthesis of a tridecasaccharide motif from Bacteroides vulgatus lipopolysaccharides by a strategy involving orthogonal one‐pot glycosylation reactions based on glycosyl ortho‐(1‐phenylvinyl)benzoates, which avoided issues such as aglycone transfer and the unpleasant odor of thioglycoside‐based orthogonal one‐pot glycosylation.