Modification of ricinoleic acid based nonisocyanate polyurethane using polyamine containing polyhedral oligomeric silsesquioxane

Biomass‐based polymers and their property regulation using functional materials have attracted much interest. In this work, ricinoleic acid‐derived cyclic carbonate was prepared and applied to the synthesis of nonisocyanate polyurethane (NIPU) with aliphatic diamine, in which octa(aminopropyl) polyhedral oligomeric silsesquioxane (OAP‐POSS) was incorporated as polyamine to partially or totally substitutes for the diamine to introduce POSS units into the polymer thus regulating the properties of the resultant material. In the curing process, Fourier transform infrared spectroscopy (FT‐IR) was used to track the reaction and curing at 50°C for 12 h was found to be sufficient for the polymerization. A series of POSS modified NIPUs were obtained by altering the molar fraction of OAP‐POSS in total amine components and the material with the highest thermal stability, shore hardness and water resistance was accessed with 100% substitution of OAP‐POSS for diamine. Polyhedral oligomeric silsesquioxane units were incorporated in the ricinoleic acid based nonisocyanate polyurethane to increase the thermal stability, shore hardness and water resistance of the material.