Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)
Pd‐NO2‐UiO‐66 for DMC Catalysis In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In...
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| Veröffentlicht in: | Small (Weinheim an der Bergstrasse, Germany) Germany), 2023-05, Vol.19 (18), p.n/a |
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| creator | Wu, Han‐Ying Qin, Ye‐Yan Xiao, Yi‐Hong Chen, Jian‐Shan Ye, Runping Guo, Rong Yao, Yuan‐Gen |
| description | Pd‐NO2‐UiO‐66 for DMC Catalysis
In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the ‐NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC. |
| doi_str_mv | 10.1002/smll.202370125 |
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In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the ‐NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC.</description><identifier>ISSN: 1613-6810</identifier><identifier>EISSN: 1613-6829</identifier><identifier>DOI: 10.1002/smll.202370125</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>acid‐base properties ; Alkalinity ; Catalysis ; Chemisorption ; dimethyl carbonate (DMC) catalysis ; functionalization ; Metal-organic frameworks ; Nanotechnology ; Nitrogen dioxide ; Palladium</subject><ispartof>Small (Weinheim an der Bergstrasse, Germany), 2023-05, Vol.19 (18), p.n/a</ispartof><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fsmll.202370125$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fsmll.202370125$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Wu, Han‐Ying</creatorcontrib><creatorcontrib>Qin, Ye‐Yan</creatorcontrib><creatorcontrib>Xiao, Yi‐Hong</creatorcontrib><creatorcontrib>Chen, Jian‐Shan</creatorcontrib><creatorcontrib>Ye, Runping</creatorcontrib><creatorcontrib>Guo, Rong</creatorcontrib><creatorcontrib>Yao, Yuan‐Gen</creatorcontrib><title>Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)</title><title>Small (Weinheim an der Bergstrasse, Germany)</title><description>Pd‐NO2‐UiO‐66 for DMC Catalysis
In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the ‐NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC.</description><subject>acid‐base properties</subject><subject>Alkalinity</subject><subject>Catalysis</subject><subject>Chemisorption</subject><subject>dimethyl carbonate (DMC) catalysis</subject><subject>functionalization</subject><subject>Metal-organic frameworks</subject><subject>Nanotechnology</subject><subject>Nitrogen dioxide</subject><subject>Palladium</subject><issn>1613-6810</issn><issn>1613-6829</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkL1OwzAUhS0EEqWwMltigSGt7dT5GUuhgBTUoXS2HMdpXdwEbAcUJmYmnpEnwVGhjEz3XN3vXB0dAE4xGmCEyNButB4QRMIYYUL3QA9HOAyihKT7O43RITiydo1QiMko7oGPy7q2TlVLOBZOvSjXQl4VcC61_N3rEi7U7Ov9M4qgW5m6Wa48rAp_G471I9eq6rBpU3lHXfn9jXcCqgpeqY10q1bDCTe5vznpleO6tcrC8_mGaw1xMuxSXxyDg5JrK09-Zh8sptcPk9sgm93cTcZZIDCNaUCKPMaUJ6GQAsUkSkdJyBMkhSBlKHAio5jmKc-LiJOcpiQWJacp5TmPSCo83Adn279Ppn5upHVsXTfG57aMJCihBI9I6KnBlhKmttbIkj0ZteGmZRixrm_W9c12fXtDujW8Ki3bf2g2v8-yP-83djKGPA</recordid><startdate>20230501</startdate><enddate>20230501</enddate><creator>Wu, Han‐Ying</creator><creator>Qin, Ye‐Yan</creator><creator>Xiao, Yi‐Hong</creator><creator>Chen, Jian‐Shan</creator><creator>Ye, Runping</creator><creator>Guo, Rong</creator><creator>Yao, Yuan‐Gen</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20230501</creationdate><title>Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)</title><author>Wu, Han‐Ying ; Qin, Ye‐Yan ; Xiao, Yi‐Hong ; Chen, Jian‐Shan ; Ye, Runping ; Guo, Rong ; Yao, Yuan‐Gen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1575-2db715a83cec07269483a80ecc2f3c18e675b9abd6a2b5927cfa595aba629c483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>acid‐base properties</topic><topic>Alkalinity</topic><topic>Catalysis</topic><topic>Chemisorption</topic><topic>dimethyl carbonate (DMC) catalysis</topic><topic>functionalization</topic><topic>Metal-organic frameworks</topic><topic>Nanotechnology</topic><topic>Nitrogen dioxide</topic><topic>Palladium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wu, Han‐Ying</creatorcontrib><creatorcontrib>Qin, Ye‐Yan</creatorcontrib><creatorcontrib>Xiao, Yi‐Hong</creatorcontrib><creatorcontrib>Chen, Jian‐Shan</creatorcontrib><creatorcontrib>Ye, Runping</creatorcontrib><creatorcontrib>Guo, Rong</creatorcontrib><creatorcontrib>Yao, Yuan‐Gen</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wu, Han‐Ying</au><au>Qin, Ye‐Yan</au><au>Xiao, Yi‐Hong</au><au>Chen, Jian‐Shan</au><au>Ye, Runping</au><au>Guo, Rong</au><au>Yao, Yuan‐Gen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)</atitle><jtitle>Small (Weinheim an der Bergstrasse, Germany)</jtitle><date>2023-05-01</date><risdate>2023</risdate><volume>19</volume><issue>18</issue><epage>n/a</epage><issn>1613-6810</issn><eissn>1613-6829</eissn><abstract>Pd‐NO2‐UiO‐66 for DMC Catalysis
In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the ‐NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/smll.202370125</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | acid‐base properties Alkalinity Catalysis Chemisorption dimethyl carbonate (DMC) catalysis functionalization Metal-organic frameworks Nanotechnology Nitrogen dioxide Palladium |
| title | Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023) |
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