Boosting Activity and Selectivity of UiO‐66 through Acidity/Alkalinity Functionalization in Dimethyl Carbonate Catalysis (Small 18/2023)

Pd‐NO2‐UiO‐66 for DMC Catalysis In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Small (Weinheim an der Bergstrasse, Germany) Germany), 2023-05, Vol.19 (18), p.n/a
Hauptverfasser:	Wu, Han‐Ying, Qin, Ye‐Yan, Xiao, Yi‐Hong, Chen, Jian‐Shan, Ye, Runping, Guo, Rong, Yao, Yuan‐Gen
Format:	Artikel
Sprache:	eng
Schlagworte:	acid‐base properties Alkalinity Catalysis Chemisorption dimethyl carbonate (DMC) catalysis functionalization Metal-organic frameworks Nanotechnology Nitrogen dioxide Palladium
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	Pd‐NO2‐UiO‐66 for DMC Catalysis In article number 2208238, Ye‐Yan Qin, Yuan‐Gen Yao, and co‐workers first introduce acidity/alkalinity functionalized metal–organic frameworks (MOFs) into dimethyl carbonate (DMC) catalysis, and the Lewis acidic Pd‐NO2‐UiO‐66 exhibits excellent catalytic behavior. In addition to affecting the interaction of Pd(II) and support, the ‐NO2 group has a dominant role in the chemisorption of methyl nitrite (MN) and CO for generating DMC.
ISSN:	1613-6810 1613-6829
DOI:	10.1002/smll.202370125