Overtone Frequencies of NO2 using Lie algebraic model

In this paper, we used the one dimensional unitatry Lie algebraic model to compute the vibrational frequencies of nitrogen dioxide (NO2) molecule in the gas phase up to the sixth overtone. In this model, the Hamiltonian operator describes the stretching and bending vibrations with algebraic parameters. The calculated fundamental vibrational frequencies are compared with experimental values and results consistent with the reference values.