Mechanism of Formation of N-Methyl-N-[2-(diphenylphosphoryl)-ethyl]amide of (Diphenylphosphoryl)acetic Acid
The mechanism of formation of N -methyl-2-(diphenylphosphoryl)acetamide was studied by DFT. The first stage, the reaction of trichlorophosphine with 2-(diphenylphosphoryl)acetic acid, involves three elementary steps, and the explicit inclusion of solvent makes it possible to reduce the activation en...
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Veröffentlicht in: | Russian journal of organic chemistry 2023-02, Vol.59 (2), p.265-269 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The mechanism of formation of
N
-methyl-2-(diphenylphosphoryl)acetamide was studied by DFT. The first stage, the reaction of trichlorophosphine with 2-(diphenylphosphoryl)acetic acid, involves three elementary steps, and the explicit inclusion of solvent makes it possible to reduce the activation energy of each of them. The second stage, the reaction of 2-(diphenylphosphoryl)acetyl chloride with a phosphoryl-substituted amine, involves one elementary step. |
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ISSN: | 1070-4280 1608-3393 |
DOI: | 10.1134/S1070428023020069 |