Synthesis and characterization of different binary and ternary phase mixtures of mesoporous nanocrystalline titanium dioxide

Different phase compositions of mesoporous nanocrystalline TiO 2 (meso-nc-TiO 2 ), comprised of anatase (16–100%), rutile (0–70%) and brookite (0–52%) were obtained by sol–gel synthesis with or without hydrothermal treatment (HTT) by means of titanium tetrabutoxide and dibenzo-18-croun-6 as structure-forming agent in the presence of HCl. It was shown, that small amounts of surfactant and/or lanthanum salt as well as HTT determine phase composition and texture of meso-nc-TiO 2. All samples were calcined at 500 о С and characterized by SEM, TEM, XRD and N 2 -adsorption/desorption isotherms. It has been established that photocatalytic properties of almost all obtained samples significantly exceed the photocatalytic activity of Evonik P-25 TiO 2 in gas phase ethanol oxidation. The most active sample is characterized by phase composition of anatase (97%)-rutile (3%). It is obvious, that decrease of photocatalytic activity of sample was affected by decrease of anatase phase content. It was shown that the specific surface area of the sample is not a key factor affecting the activity of mixed-phase meso-nc-TiO 2 samples in the process of ethanol oxidation.