Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex
Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt...
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Veröffentlicht in: | Wuhan University journal of natural sciences 1999, Vol.4 (1), p.82-84 |
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description | Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt complex exhibits high regioselectivty for styrene, nearly 100% branched product is obtained. |
doi_str_mv | 10.1007/BF02827629 |
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The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt complex exhibits high regioselectivty for styrene, nearly 100% branched product is obtained.</description><subject>Alkenes</subject><subject>Amination</subject><subject>Chemical synthesis</subject><subject>Coordination compounds</subject><subject>Fullerenes</subject><subject>Hydrosilylation</subject><subject>Metal complexes</subject><subject>Noble metals</subject><subject>Platinum</subject><subject>Rhodium</subject><subject>Styrene</subject><issn>1007-1202</issn><issn>1993-4998</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1999</creationdate><recordtype>article</recordtype><recordid>eNpFUE1LxDAQDaLgunrxFwS8yVYzSdtsjiquCgse1JNISdOEZumXSSpW_PFm2QUv88F782bmIXQO5AoI4de3K0KXlOdUHKAZCMGSVIjlYawjmgAl9BideL8hhImMwwz9vkxdqLW3foFVLZ1UQTv7I4PtOyy7CisZZDMFq3A9Va73tpmaPaqC_bJhwr3B7zn5wGZsGu10p3GXDK4fIrG1sRu2A93YLrCr-8qOLVZ9OzT6-xQdGdl4fbbPc_S2un-9e0zWzw9PdzfrRAGDkHCoFIU8Y0aKjDIK3JQxEiGqNDcpLGWpVMZoaQSkSqaKEllq0BUnOldA2Bxd7HTjVZ-j9qHY9KPr4sqC8mUuGHC-ZV3uWCq-6Z02xeBsK91UACm2_hX_7rI_PDlutg</recordid><startdate>1999</startdate><enddate>1999</enddate><creator>Pengfei, Fang</creator><creator>Yuanyin, Chen</creator><creator>Ling, Hu</creator><creator>Qiusheng, Lu</creator><creator>Ling, Zhu</creator><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>1999</creationdate><title>Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex</title><author>Pengfei, Fang ; Yuanyin, Chen ; Ling, Hu ; Qiusheng, Lu ; Ling, Zhu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c131t-71dc21653fa9523217fb321099d46f418abcc532bf914ca4c20abe1ed70e6c103</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1999</creationdate><topic>Alkenes</topic><topic>Amination</topic><topic>Chemical synthesis</topic><topic>Coordination compounds</topic><topic>Fullerenes</topic><topic>Hydrosilylation</topic><topic>Metal complexes</topic><topic>Noble metals</topic><topic>Platinum</topic><topic>Rhodium</topic><topic>Styrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pengfei, Fang</creatorcontrib><creatorcontrib>Yuanyin, Chen</creatorcontrib><creatorcontrib>Ling, Hu</creatorcontrib><creatorcontrib>Qiusheng, Lu</creatorcontrib><creatorcontrib>Ling, Zhu</creatorcontrib><collection>CrossRef</collection><jtitle>Wuhan University journal of natural sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pengfei, Fang</au><au>Yuanyin, Chen</au><au>Ling, Hu</au><au>Qiusheng, Lu</au><au>Ling, Zhu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex</atitle><jtitle>Wuhan University journal of natural sciences</jtitle><date>1999</date><risdate>1999</risdate><volume>4</volume><issue>1</issue><spage>82</spage><epage>84</epage><pages>82-84</pages><issn>1007-1202</issn><eissn>1993-4998</eissn><abstract>Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt complex exhibits high regioselectivty for styrene, nearly 100% branched product is obtained.</abstract><cop>Heidelberg</cop><pub>Springer Nature B.V</pub><doi>10.1007/BF02827629</doi><tpages>3</tpages></addata></record> |
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subjects | Alkenes Amination Chemical synthesis Coordination compounds Fullerenes Hydrosilylation Metal complexes Noble metals Platinum Rhodium Styrene |
title | Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex |
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