Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex

Synthesis, characterization and catalytic hydrosilylation activity of [60] fullerene n-propylamine platinum, rhodium complex

Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt...

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Veröffentlicht in:Wuhan University journal of natural sciences 1999, Vol.4 (1), p.82-84
Hauptverfasser: Pengfei, Fang, Yuanyin, Chen, Ling, Hu, Qiusheng, Lu, Ling, Zhu
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Amination
Chemical synthesis
Coordination compounds
Fullerenes
Hydrosilylation
Metal complexes
Noble metals
Platinum
Rhodium
Styrene
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Zusammenfassung:Fullerenen-propylamine platinum, rhodium complex have been prepared from C60 via amination withn-propylamine, then reacting respectively with potassium chloroplatinite or rhodium chloride. The two noble metal complexes can effectively catalyze hydrosiiylation of olefins with triethoxysilane. The Pt complex exhibits high regioselectivty for styrene, nearly 100% branched product is obtained.
ISSN:1007-1202
1993-4998
DOI:10.1007/BF02827629