Life tests of lithium/fluorocarbon cells

Long-term (15 years) tests of lithium/fluorocarbon cells (Li-CFx) are performed using the full-scale and accelerated storage in a wide temperature range. Regularities governing the capacity loss of the cells in different storage modes are discovered. The self-discharge rate constants are determined...

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Veröffentlicht in:Russian journal of electrochemistry 2000-07, Vol.36 (7), p.778-783
1. Verfasser: Fateev, S. A.
Format: Artikel
Sprache:eng
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Zusammenfassung:Long-term (15 years) tests of lithium/fluorocarbon cells (Li-CFx) are performed using the full-scale and accelerated storage in a wide temperature range. Regularities governing the capacity loss of the cells in different storage modes are discovered. The self-discharge rate constants are determined for different temperatures. A mechanism is proposed, which explains the cell self-discharge by the occurrence of a number of chemical reactions that lead to the loss of active fluorine and the electrode passivation. The activation energy for the self-discharge process is determined
ISSN:1023-1935
1608-3342
DOI:10.1007/BF02757680