Studies on a selena-aza-crown ether: Synthesis and catalytic behavior in hydrosilylation

Studies on a selena-aza-crown ether: Synthesis and catalytic behavior in hydrosilylation

The synthesis of a new type of selena-aza crown ether-6-(4-nitrobenzyl)-1,4,7,10-selenatriazacyclododecane (L) derivated from phenylalamine, and its platinum (II) complex was described. The catalytic activity of this complex for the hydrosilylation of olefins by triethoxysilane was investigated.

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Veröffentlicht in:Wuhan University journal of natural sciences 1997-12, Vol.2 (4), p.464-466
Hauptverfasser: Wei, Xu, Xiufang, Liu, Xueran, Lu, Hansheng, Xu
Format: Artikel
Sprache:eng
Schlagworte:
Alkenes
Catalytic activity
Chemical synthesis
Crown ethers
Hydrosilylation
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Zusammenfassung:The synthesis of a new type of selena-aza crown ether-6-(4-nitrobenzyl)-1,4,7,10-selenatriazacyclododecane (L) derivated from phenylalamine, and its platinum (II) complex was described. The catalytic activity of this complex for the hydrosilylation of olefins by triethoxysilane was investigated.
ISSN:1007-1202
1993-4998
DOI:10.1007/BF02830258