Kinetics of the transfer of the dimethyl-carbamoyl group from N- and O-acylonium salts to azines and their N-oxides

The rate constants and activation energies were determined for a series of reactions involving the transfer of a dimethylcarbamoyl group from the N,N-dimethylcarbamoylonium salts of a series of nitrogen heterocycles and their N-oxides to nucleophiles (azines and their N-oxides) in acetonitrile. The measured values were compared with the structural, reaction, and equilibrium characteristics.