Growth of ferroelectric lead metatantalate single crystals

Liquidus relations in the “Pb(BO2)2”-PbTa2O6, Pb(VO3)2-PbTa2O6, and Pb2V2O7 —PbTa2O6 systems were studied in order to find solvents for growing ferroelectric lead metatantalate single crystals below 1300‡C. PbO-V2O5 melts were shown to be suitable solvents for growing lead metatantalate crystals wit...

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Veröffentlicht in:Inorganic materials 2000-11, Vol.36 (11), p.1161-1163
Hauptverfasser: Sholokhovich, M. L., Dugin, V. E., Rybina, I. N.
Format: Artikel
Sprache:eng
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Zusammenfassung:Liquidus relations in the “Pb(BO2)2”-PbTa2O6, Pb(VO3)2-PbTa2O6, and Pb2V2O7 —PbTa2O6 systems were studied in order to find solvents for growing ferroelectric lead metatantalate single crystals below 1300‡C. PbO-V2O5 melts were shown to be suitable solvents for growing lead metatantalate crystals with both rhombohedral and tetragonal potassium tungsten bronze structures. Ferroelectric PbTa2O6 crystals with a Curie temperature of 265‡C were grown from vanadate fluxes.
ISSN:0020-1685
1608-3172
DOI:10.1007/BF02758938