Synthesis, Structure, and Properties of 2-Oxo-3-formylquinolone Acylhydrazone Containing a Trimethylammonium Fragment and also of Transition Metal Complexes Based on This Compound

The product of 3-formyl-2-quinolone condensation with trimethylammonium chloride acethydrazide, (H 2 L + )Сl – hydrazone, was synthesized. Complexes of Zn(II) and Cu(II), [M(HL)OCH 3 ]ClO 4 , with a distorted square-planar strucrure of coordination sites and asymmetric chelate сomplexes of Mn(II), N...

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Veröffentlicht in:Russian journal of general chemistry 2022-12, Vol.92 (12), p.2796-2808
Hauptverfasser: Popov, L. D., Tupolova, Yu. P., Vlasenko, V. G., Borodkin, S. A., Levchenkov, S. I., Lebedev, V. E., Askalepova, O. I., Borodkin, G. S., Zubenko, A. A., Gishko, K. B., Zubavichus, Ya. V., Lazarenko, V. A., Shcherbakov, I. N.
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Sprache:eng
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Zusammenfassung:The product of 3-formyl-2-quinolone condensation with trimethylammonium chloride acethydrazide, (H 2 L + )Сl – hydrazone, was synthesized. Complexes of Zn(II) and Cu(II), [M(HL)OCH 3 ]ClO 4 , with a distorted square-planar strucrure of coordination sites and asymmetric chelate сomplexes of Mn(II), Ni(II), and Co(II), [M(HL)(H 2 L)]·(ClO 4 ) 3 , of pseudo-octahedral structure were obtained on its basis. The protistocidal, antibacterial, and fungistatic activities of the synthesized compounds were studied.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363222120301