Limited ionicity in poor protic ionic liquids: Association Gibbs energies

Limited ionicity in poor protic ionic liquids: Association Gibbs energies

Protic ionic liquids (PILs), made from anhydrous mixtures of Bronsted acids HA and bases B (HA + B → BH+ + A−), occasionally suffer from limited ionicity. In cases of “poor” PILs (

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Veröffentlicht in:The Journal of chemical physics 2023-01, Vol.158 (3), p.034507-034507
Hauptverfasser: Klapatiuk, Devin O., Waugh, Shawn L., Mukadam, Abdulrahman A., East, Allan L. L.
Format: Artikel
Sprache:eng
Schlagworte:
Amines
Associations
Autoionization
Carboxylic Acids
Dielectric strength
Dipoles
Disproportionation
Ion pairs
Ionic Liquids
Ions
Mathematical analysis
Mixing ratio
Mixtures
Permittivity
Physics
Protons
Quantum chemistry
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Beschreibung
Zusammenfassung:Protic ionic liquids (PILs), made from anhydrous mixtures of Bronsted acids HA and bases B (HA + B → BH+ + A−), occasionally suffer from limited ionicity. In cases of “poor” PILs (
ISSN:0021-9606
1089-7690
DOI:10.1063/5.0124900