Enhanced gravimetric capacitance of CeO2 by compositing with the hybridized phase of MoS2
The low electrical conductivity of CeO 2 hinders its gravimetric capacitance (C S ) despite its good redox property. Therefore, this work aims to improve the gravimetric capacitance of CeO 2 , by compositing it with a suitable material. Here, the oxygen-incorporated 1T/2H hybrid MoS 2 is composited...
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Veröffentlicht in: | Ionics 2023-02, Vol.29 (2), p.843-852 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
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Zusammenfassung: | The low electrical conductivity of CeO
2
hinders its gravimetric capacitance (C
S
) despite its good redox property. Therefore, this work aims to improve the gravimetric capacitance of CeO
2
, by compositing it with a suitable material. Here, the oxygen-incorporated 1T/2H hybrid MoS
2
is composited with CeO
2
(CeO
2
/O-MoS
2
), as it improves the electrical conductivity and C
S
. This is evident from the enhanced gravimetric capacitance value of 429.41 F/g at 0.5 A/g in 0.5 M of H
2
SO
4
by the CeO
2
/O-MoS
2
composite, compared to the low value of 87.76 F/g of pristine CeO
2
. The lower electrochemical impedance values of the composite concur with the enhanced gravimetric capacitance of the composite, compared to the pristine CeO
2
. The same composite in a symmetric two-electrode system at 0.5 A/g showed a gravimetric capacitance value of 167.37 F/g with 95.49% capacitance retention after 4000 cycles at 10 A/g in 0.5 M of H
2
SO
4
. |
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ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-022-04846-3 |