SYNTHESIS AND STRUCTURE OF THE LINEAR BIMETALLIC ACETATE-PHENANTHROLINE COORDINATION POLYMER BASED ON PALLADIUM(II) AND NICKEL(II) IN A 2:1 METAL-TO-METAL RATIO

By the interaction of 1,10-phenanthroline with the heterobinuclear acetate complex PdNi(OOCMe) 4 a new heteronuclear acetate-bridged coordination polymer [Pd(OOCMe) 4 Ni·(OOCMe) 2 Pd(phen)2MeCN] n ( I ), in which phenanthroline is coordinated with palladium atom, is synthesized and its structure is...

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Veröffentlicht in:	Journal of structural chemistry 2022-12, Vol.63 (12), p.1997-2003
Hauptverfasser:	Yakushev, I. A., Sosunov, E. A., Makarevich, Yu. E., Maksimova, A. D., Nesterenko, M. Yu, Vargaftik, M. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic Atomic/Molecular Structure and Spectra Bimetals Chemistry Chemistry and Materials Science Coordination polymers Inorganic Chemistry Molecular Optical and Plasma Physics Palladium Physical Chemistry Single crystals Solid State Physics
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Beschreibung
Zusammenfassung:	By the interaction of 1,10-phenanthroline with the heterobinuclear acetate complex PdNi(OOCMe) 4 a new heteronuclear acetate-bridged coordination polymer [Pd(OOCMe) 4 Ni·(OOCMe) 2 Pd(phen)2MeCN] n ( I ), in which phenanthroline is coordinated with palladium atom, is synthesized and its structure is characterized by single crystal XRD.
ISSN:	0022-4766 1573-8779
DOI:	10.1134/S0022476622120113