Hydrogen generation from methanol steam reforming process of CuCrO2-CeO2 nanopowders catalyst
Methanol Steam Reforming Process Over 50CuCrO2-50CeO2 nanopowders. [Display omitted] •CuCrO2-CeO2 nanopowders were prepared by a self-combusted glycine nitrate process.•The prepared 50CuCrO2-50CeO2 nanopowders were applied for the methanol steam reforming.•The surface area of CuCrO2-CeO2 nanopowders...
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Veröffentlicht in: | Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2022-12, Vol.286, p.115989, Article 115989 |
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Sprache: | eng |
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Zusammenfassung: | Methanol Steam Reforming Process Over 50CuCrO2-50CeO2 nanopowders.
[Display omitted]
•CuCrO2-CeO2 nanopowders were prepared by a self-combusted glycine nitrate process.•The prepared 50CuCrO2-50CeO2 nanopowders were applied for the methanol steam reforming.•The surface area of CuCrO2-CeO2 nanopowders varied from 28.02 m2/g to 45.72 m2/g.•The 50CuCrO2-50CeO2 nanopowders exhibited hydrogen production rate as 2059.65 ml STP min−1 g-cat−1 at 400 °C.
Hydrogen (H2) is under consideration as an alternative renewable energy transporter due to the energy crisis and climate change. In this research, CuCrO2-CeO2 nanopowders catalysts were synthesized through the glycine nitrate process and utilized in the SRM process. The prepared CuCrO2-CeO2 nanopowders were characterized by different characterization techniques. The nanosized CuCrO2-CeO2 nanopowders particles were confirmed by HRTEM to be around 10–15 nm in size. The specific surface area of the CuCrO2-CeO2 powders varied from 28.02 m2/g to 45.72 m2/g. The 50CuCrO2-50CeO2 powder was applied in the SRM process and exhibited the highest H2 production rate of 2059.65 ml STP min−1 g-cat−1 at 400 °C. Furthermore, the H2 production rate of the 50CuCrO2-50CeO2 nanopowders were increased by the added CeO2. The porous structure of the catalyst presents advantages in the SRM process, such as low cost, simplicity, and rapidity. As a result, the 50CuCrO2-50CeO2 nanopowders could have significant economic future. |
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ISSN: | 0921-5107 1873-4944 |
DOI: | 10.1016/j.mseb.2022.115989 |