Development of HLW Partitioning Technologies in Extraction Systems Based on Different Radical Phosphine Oxide in Heavy Diluents at “PA Mayak”

Development of HLW Partitioning Technologies in Extraction Systems Based on Different Radical Phosphine Oxide in Heavy Diluents at “PA Mayak”

“Mayak” production association has convincingly demonstrated the possibility of creating a HLW partitioning scheme based on different radical phosphine oxide in heavy fluorinated or chlorinated diluents, including in the presence of tributyl phosphate. The separation system makes it possible to effi...

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Veröffentlicht in:Radiochemistry (New York, N.Y.) N.Y.), 2022-10, Vol.64 (5), p.581-602
Hauptverfasser: Logunov, M. V., Voroshilov, Yu. A., Babain, V. A.
Format: Artikel
Sprache:eng
Schlagworte:
Actinides
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Neptunium
Nuclear Chemistry
Partitioning
Phosphine oxide
Plutonium
Technetium
Uranium
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Zusammenfassung:“Mayak” production association has convincingly demonstrated the possibility of creating a HLW partitioning scheme based on different radical phosphine oxide in heavy fluorinated or chlorinated diluents, including in the presence of tributyl phosphate. The separation system makes it possible to efficiently recover uranium, plutonium, neptunium, REE–TPE, as well as technetium from solutions (up to 2 M) in HNO 3 and separate them into at least two fractions: a fraction of trivalent REE/TPE with the bulk of technetium and a fraction of polyvalent actinides.
ISSN:1066-3622
1608-3288
DOI:10.1134/S1066362222050022