Photo‐induced Cobalt‐catalyzed Aerobic N−N Coupling of Diarylamines at Room Temperature

We report herein a photo induced Co‐catalyzed aerobic N−N coupling of diarylamines to form the corresponding tetraarylhydrazines. In this protocol, the N−N coupling reactions could be realized under mild conditions in the presence of Co(OAc)2 ⋅ 4H2O and BPhen with the irradiation of light (390–395 n...

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Veröffentlicht in:Asian journal of organic chemistry 2022-12, Vol.11 (12), p.n/a
Hauptverfasser: Luo, Guanzhong, Han, Yu, Zhang, Ruohan, Ding, Dongmiao, Dian, Longyang
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Sprache:eng
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Zusammenfassung:We report herein a photo induced Co‐catalyzed aerobic N−N coupling of diarylamines to form the corresponding tetraarylhydrazines. In this protocol, the N−N coupling reactions could be realized under mild conditions in the presence of Co(OAc)2 ⋅ 4H2O and BPhen with the irradiation of light (390–395 nm). We report herein a photo induced Co‐catalyzed aerobic N−N coupling of diarylamines to form the corresponding tetraarylhydrazines. In this protocol, the N−N coupling reactions could be realized under mild conditions in the presence of Co(OAc)2 ⋅ 4H2O and BPhen with the irradiation of light (390–395 nm).
ISSN:2193-5807
2193-5815
DOI:10.1002/ajoc.202200553