Alkali Metal–Metal Exchange Reaction for Effective Synthesis of Functional Phosphate Salts

Alkali Metal–Metal Exchange Reaction for Effective Synthesis of Functional Phosphate Salts

AMPO4 and MPO4 systems (A = alkali metal, M = metal) exhibit various optical and electrochemical functions. This study shows that such systems can be synthesized via an alkali metal–metal exchange reaction between A3PO4 and the metal salt of an acid with lower pKa than phosphoric acid. This method s...

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Veröffentlicht in:Chemistry letters 2022-11, Vol.51 (11), p.1099-1101
Hauptverfasser: Nagata, Hiroshi, Nakajima, Tomohiko, Akimoto, Junji, Kataoka, Kunimitsu
Format: Artikel
Sprache:eng ; jpn
Schlagworte:
Chemical synthesis
Phosphoric acid
System effectiveness
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Zusammenfassung:AMPO4 and MPO4 systems (A = alkali metal, M = metal) exhibit various optical and electrochemical functions. This study shows that such systems can be synthesized via an alkali metal–metal exchange reaction between A3PO4 and the metal salt of an acid with lower pKa than phosphoric acid. This method significantly improves the material designs and syntheses of various phosphate salts.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.220388