STUDY OF [Pd(NH3)4](MoO4)x(CrO4)1–x SOLID SOLUTIONS AND PRODUCTS OF THEIR THERMOLYSIS
By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH 3 ) 4 ]MoO 4 and [Pd(NH 3 ) 4 ]CrO 4 salts, [Pd(NH 3 ) 4 ](MoO 4 ) x (CrO 4 ) 1– x solid solutions with x ranging from 0.05 to 0.80 are formed. To construct the V ( x ) dependence an original...
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| Veröffentlicht in: | Journal of structural chemistry 2022-11, Vol.63 (11), p.1856-1871 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | By the single crystal X-ray diffraction (XRD) analysis it is shown that on slow co-crystallization of [Pd(NH
3
)
4
]MoO
4
and [Pd(NH
3
)
4
]CrO
4
salts, [Pd(NH
3
)
4
](MoO
4
)
x
(CrO
4
)
1–
x
solid solutions with
x
ranging from 0.05 to 0.80 are formed. To construct the
V
(
x
) dependence an original procedure of refining unit cell parameters is used. It is revealed that in the thermal decomposition of the [Pd(NH
3
)
4
](MoO
4
)
0.18
(CrO
4
)
0.82
single crystal (composition is determined by the single crystal XRD analysis) a mixture of phases based on the fcc lattice of Pd (Pd
0.88
Cr
0.10
Mo
0.01
) and on Cr
2
O
3
is formed. |
|---|---|
| ISSN: | 0022-4766 1573-8779 |
| DOI: | 10.1134/S0022476622110166 |