Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study
In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane...
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| Veröffentlicht in: | Indian journal of chemical technology 2022-11, Vol.29 (6), p.721 |
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| container_title | Indian journal of chemical technology |
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| creator | Sathiyaraj, M Ramya, R Tamizharasu, G Rajendran, V Venkatesh, P |
| description | In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane-1,2-diaminium dibromide (MPTC). The pseudo first-order kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of 4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and reduces the time consumption. The activation energy (Ea) has been calculated from the experimental results. |
| doi_str_mv | 10.56042/ijct.v29i6.67419 |
| format | Article |
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The pseudo first-order kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of 4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and reduces the time consumption. 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The pseudo first-order kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of 4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and reduces the time consumption. The activation energy (Ea) has been calculated from the experimental results.</description><subject>Biphenyl</subject><subject>Catalysts</subject><subject>High temperature</subject><subject>Kinetic equations</subject><subject>Phase transfer catalysts</subject><subject>Selectivity</subject><subject>Sonication</subject><issn>0971-457X</issn><issn>0975-0991</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNotkM1KxDAUhYMoOI4-gLuAG110TJufNsth8A8GXKjgrqRpajN2kjFJ1YoL38E39EmMHVfnwDn3Xu4HwHGKZpQhkp3rlQyz14xrNmM5SfkOmCCe0wRxnu6OPk0IzR_3wYH3K4QY5UU-AZ93gwmt8tpD20CSnFbKfAydfR_OKr1plRk62JtaOSjguu-CTrwOCm5a4VUSnDC-iZkUQXSDD1B01jzBNx1aGMtOeGt0DLU18OfrG87hszYqaAl96OvhEOw1ovPq6F-n4OHy4n5xnSxvr24W82Uis4yGRNCUKUwLQiWNhsmMNTgqLjJc8FqKigqZx5cwphSpmkuiZC6IaGjFakXxFJxs926cfemVD-XK9s7Ek2WWY07yLA7GVrptSWe9d6opN06vhRvKFJUj5PIPcjlCLkfI-BdllXTG</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Sathiyaraj, M</creator><creator>Ramya, R</creator><creator>Tamizharasu, G</creator><creator>Rajendran, V</creator><creator>Venkatesh, P</creator><general>Publications and Information Directorate, Council on Scientific and Industrial Research</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7U5</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>L7M</scope></search><sort><creationdate>20221101</creationdate><title>Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study</title><author>Sathiyaraj, M ; Ramya, R ; Tamizharasu, G ; Rajendran, V ; Venkatesh, P</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c225t-a516e35845c56e36c26f3e36382389dcab5ac700633550ed9c4ec7a4af5b6de53</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Biphenyl</topic><topic>Catalysts</topic><topic>High temperature</topic><topic>Kinetic equations</topic><topic>Phase transfer catalysts</topic><topic>Selectivity</topic><topic>Sonication</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sathiyaraj, M</creatorcontrib><creatorcontrib>Ramya, R</creatorcontrib><creatorcontrib>Tamizharasu, G</creatorcontrib><creatorcontrib>Rajendran, V</creatorcontrib><creatorcontrib>Venkatesh, P</creatorcontrib><collection>CrossRef</collection><collection>Aqualine</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Indian journal of chemical technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sathiyaraj, M</au><au>Ramya, R</au><au>Tamizharasu, G</au><au>Rajendran, V</au><au>Venkatesh, P</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study</atitle><jtitle>Indian journal of chemical technology</jtitle><date>2022-11-01</date><risdate>2022</risdate><volume>29</volume><issue>6</issue><spage>721</spage><pages>721-</pages><issn>0971-457X</issn><eissn>0975-0991</eissn><abstract>In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane-1,2-diaminium dibromide (MPTC). 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| issn | 0971-457X 0975-0991 |
| language | eng |
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| source | DOAJ Directory of Open Access Journals; EZB-FREE-00999 freely available EZB journals; Free Full-Text Journals in Chemistry |
| subjects | Biphenyl Catalysts High temperature Kinetic equations Phase transfer catalysts Selectivity Sonication |
| title | Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study |
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