Synthesis of 4-(benzyloxy)biphenyl under a multi-site phase-transfer catalyst along with ultrasonication – A kinetic study

In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Indian journal of chemical technology 2022-11, Vol.29 (6), p.721
Hauptverfasser: Sathiyaraj, M, Ramya, R, Tamizharasu, G, Rajendran, V, Venkatesh, P
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In this present study, the synthesis of 4-(benzyloxy)biphenyl has been successfully carried out using 4-phenylphenol and benzyl chloride in the presence of ultrasonic power (40 kHz, 300W) along with synthesized multi - site phase - transfer catalyst viz., N1,N2-dibenzyl-N1,N1,N2,N2-tetramethylethane-1,2-diaminium dibromide (MPTC). The pseudo first-order kinetic equation has been applied to describe the organic reaction. The various kinetic parameters on the preparation of 4-(benzyloxy)biphenyl has been carried out under ultrasonic frequency condition and synthesized multi - site phase transfer catalyst. Sonication has resulted in better selectivity, high yield, avoids the use of the high temperature, side products and reduces the time consumption. The activation energy (Ea) has been calculated from the experimental results.
ISSN:0971-457X
0975-0991
DOI:10.56042/ijct.v29i6.67419