High-speed hydrogen sensor fabricated using a platinum/titanium oxide nanocontact

Titanium dioxide (TiO2) thin films have been extensively studied for use in solid-state hydrogen (H2) gas sensors. In this work, TiOx/platinum (Pt) nanocontacts which constitute a Schottky-diode sensor were developed using shadow evaporation. Large resistance changes and short reaction times were ac...

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Veröffentlicht in:Sensors and actuators. B, Chemical Chemical, 2022-11, Vol.371, p.132531, Article 132531
Hauptverfasser: Naitoh, Yasuhisa, Sumiya, Touru, Shima, Hisashi, Akinaga, Hiroyuki
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Sprache:eng
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Zusammenfassung:Titanium dioxide (TiO2) thin films have been extensively studied for use in solid-state hydrogen (H2) gas sensors. In this work, TiOx/platinum (Pt) nanocontacts which constitute a Schottky-diode sensor were developed using shadow evaporation. Large resistance changes and short reaction times were achieved through measurement of the resistance of the contacts. The sensing was quite depended on the thickness of the TiOx layer. The results indicate that the large sensor response over 105 was achieved just neighboring outermost surfaces of TiOx layer. As this sensor can be fabricated at temperatures less than 400 K, it is expected to be applicable to on-tip sensors. •High-speed H2 sensing were achieved using a Pt/TiOx nanocontact.•Nanocontact thickness affected the resistance and speed during H2 sensing.•The sensing times were less than 3 s at 373 K.•High temperatures were not used, making the sensor compatible with Si devices.
ISSN:0925-4005
1873-3077
DOI:10.1016/j.snb.2022.132531