Redox‐Neutral Synthesis of Polycyclic Azaheterocycles via Cobalt‐Catalyzed Hydroarylation/Annulation of Maleimides

Redox‐Neutral Synthesis of Polycyclic Azaheterocycles via Cobalt‐Catalyzed Hydroarylation/Annulation of Maleimides

Herein, we report a cobalt‐catalyzed hydroarylation of maleimides followed by an annulation sequence for the synthesis of polycyclic azaheterocycles in one pot. The reaction proceeds under redox‐neutral conditions and is compatible with various functional groups. Notably, the as‐prepared product exh...

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Veröffentlicht in:Advanced synthesis & catalysis 2022-11, Vol.364 (21), p.3730-3735
Hauptverfasser: He, Yequan, Li, Wenwei, Zhou, Honggui, Zeng, Ge, Chen, Zhongyan, Ge, Jing‐Yuan, Lv, Ningning, Chen, Jiuxi
Format: Artikel
Sprache:eng
Schlagworte:
azaheterocycles
Chemical reactions
Chemical synthesis
cobalt-catalyzed
Functional groups
hydroarylation
maleimides
Organic chemistry
photophysical properties
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Zusammenfassung:Herein, we report a cobalt‐catalyzed hydroarylation of maleimides followed by an annulation sequence for the synthesis of polycyclic azaheterocycles in one pot. The reaction proceeds under redox‐neutral conditions and is compatible with various functional groups. Notably, the as‐prepared product exhibits potential photophysical properties.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202200809