ACTIVE DIELECTRICS BASED ON COMPLEX ZIRCONIUM MOLYBDATES

ACTIVE DIELECTRICS BASED ON COMPLEX ZIRCONIUM MOLYBDATES

This work summarizes results of a study of the structure and properties of double and triple molybdates in M 2 MoO 4 – R 2 (MoO 4 ) 3 –Zr(MoO 4 ) 2 systems ( M = K, Rb, Cs, R is a triply charged cation). Features of the formation of new double and triple molybdates Ln x Zr y (MoO 4 ) z (Ln = La–Lu,...

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Veröffentlicht in:Journal of structural chemistry 2022-10, Vol.63 (10), p.1678-1696
Hauptverfasser: Bazarova, Zh. G., Subanakov, A. K., Bazarov, B. G.
Format: Artikel
Sprache:eng
Schlagworte:
Atomic
Atomic/Molecular Structure and Spectra
Cesium
Chemistry
Chemistry and Materials Science
Crystal structure
Crystallography
Inorganic Chemistry
Molecular
Molybdates
Optical and Plasma Physics
Physical Chemistry
Single crystals
Solid State Physics
Zirconium
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Zusammenfassung:This work summarizes results of a study of the structure and properties of double and triple molybdates in M 2 MoO 4 – R 2 (MoO 4 ) 3 –Zr(MoO 4 ) 2 systems ( M = K, Rb, Cs, R is a triply charged cation). Features of the formation of new double and triple molybdates Ln x Zr y (MoO 4 ) z (Ln = La–Lu, Y) and M a R b Zr c (MoO 4 ) d ( M  = K, Rb, Cs; R  = Ln, R 3+ ) are revealed, the corresponding single crystals are prepared, their structures are determined. Crystallographic, thermal, and electrophysical characteristics of individual phases are determined. The “composition–structure–properties” relation in the systems is established.
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476622100146