Fabrication of efficient and stable planar perovskite solar cell using copper oxide as hole transport material
Hole transport material (HTM) is an important component for fabricating the organometallic planar perovskite solar cells (OPSC). Metal oxide based hole transport materials are developed to increase the device stability and minimize the fabrication cost. In this article, the CuO nanoparticles (NPs) i...
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| Veröffentlicht in: | Journal of alloys and compounds 2022-11, Vol.923, p.166285, Article 166285 |
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| container_title | Journal of alloys and compounds |
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| creator | Arjun, V. Muthukumaran, K.P. Ramachandran, K. Nithya, A. Karuppuchamy, S. |
| description | Hole transport material (HTM) is an important component for fabricating the organometallic planar perovskite solar cells (OPSC). Metal oxide based hole transport materials are developed to increase the device stability and minimize the fabrication cost. In this article, the CuO nanoparticles (NPs) is prepared by precipitation, microwave and hydrothermal assisted methods and used as hole transport material for planar OPSCs. The hydrothermally prepared CuO (H-CuO) has highest power conversion efficiency (PCE) among the other devices. The power conversion efficiency is increased in the order of P-CuO |
| doi_str_mv | 10.1016/j.jallcom.2022.166285 |
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•Hole Transport Material (HTM) has been prepared for fabricating perovskite solar cells.•CuO nanoparticles used as a HTM which is prepared by solution growth techniques.•Optical, structural, morphological and elemental analyses were carried out.•CuO NPs have good interfacial contact between perovskite and carbon electrode.•The synthesized CuO NPs exhibit better photovoltaic performance.</description><identifier>ISSN: 0925-8388</identifier><identifier>EISSN: 1873-4669</identifier><identifier>DOI: 10.1016/j.jallcom.2022.166285</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Copper oxide ; Copper oxides ; Efficiency ; Electron recombination ; Energy conversion efficiency ; Hole transport material ; Metal oxides ; Nanoparticles ; Organometallic planar perovskite solar cells ; Perovskites ; Photoelectric effect ; Photovoltaic cells ; Production costs ; Solar cells ; Stability</subject><ispartof>Journal of alloys and compounds, 2022-11, Vol.923, p.166285, Article 166285</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Nov 25, 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c337t-fd7ab11de57ce95b584bcc58f76a911764d1dfd20e3f39a10d4ac335c3c9870f3</citedby><cites>FETCH-LOGICAL-c337t-fd7ab11de57ce95b584bcc58f76a911764d1dfd20e3f39a10d4ac335c3c9870f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jallcom.2022.166285$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>Arjun, V.</creatorcontrib><creatorcontrib>Muthukumaran, K.P.</creatorcontrib><creatorcontrib>Ramachandran, K.</creatorcontrib><creatorcontrib>Nithya, A.</creatorcontrib><creatorcontrib>Karuppuchamy, S.</creatorcontrib><title>Fabrication of efficient and stable planar perovskite solar cell using copper oxide as hole transport material</title><title>Journal of alloys and compounds</title><description>Hole transport material (HTM) is an important component for fabricating the organometallic planar perovskite solar cells (OPSC). Metal oxide based hole transport materials are developed to increase the device stability and minimize the fabrication cost. In this article, the CuO nanoparticles (NPs) is prepared by precipitation, microwave and hydrothermal assisted methods and used as hole transport material for planar OPSCs. The hydrothermally prepared CuO (H-CuO) has highest power conversion efficiency (PCE) among the other devices. The power conversion efficiency is increased in the order of P-CuO< M-CuO< H-CuO. The maximum photocurrent of 16.98 mA/cm2, power conversion efficiency of 7.75% and 960 h of stability was achieved with H-CuO based devices. The synthesized CuO NPs make good interfacial contact between perovskite and carbon electrode and exhibit better device performance. Experimental studies revealed that the CuO NPs acts as a HTM, which enhances the charge extraction and effectively suppresses the electron recombination in the OPSC. CuO NPs based OPSC shows good device stability as compared to P3HT based devices.
•Hole Transport Material (HTM) has been prepared for fabricating perovskite solar cells.•CuO nanoparticles used as a HTM which is prepared by solution growth techniques.•Optical, structural, morphological and elemental analyses were carried out.•CuO NPs have good interfacial contact between perovskite and carbon electrode.•The synthesized CuO NPs exhibit better photovoltaic performance.</description><subject>Copper oxide</subject><subject>Copper oxides</subject><subject>Efficiency</subject><subject>Electron recombination</subject><subject>Energy conversion efficiency</subject><subject>Hole transport material</subject><subject>Metal oxides</subject><subject>Nanoparticles</subject><subject>Organometallic planar perovskite solar cells</subject><subject>Perovskites</subject><subject>Photoelectric effect</subject><subject>Photovoltaic cells</subject><subject>Production costs</subject><subject>Solar cells</subject><subject>Stability</subject><issn>0925-8388</issn><issn>1873-4669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LxDAQhoMouK7-BCHguWvStE17EhG_YMGLnsM0mWhqtqlJVvTf22X37mlg5n1mmIeQS85WnPHmelgN4L0Om1XJynLFm6Zs6yOy4K0URdU03TFZsK6si1a07Sk5S2lgjPFO8AUZH6CPTkN2YaTBUrTWaYdjpjAamjL0HunkYYRIJ4zhO326jDQFPzc0ek-3yY3vVIdpHtPw4wxSSPQjzFyOMKYpxEw3kDE68OfkxIJPeHGoS_L2cP9691SsXx6f727XhRZC5sIaCT3nBmupsav7uq16revWygY6zmVTGW6sKRkKKzrgzFQwk7UWumsls2JJrvZ7pxi-tpiyGsI2jvNJVcqSVZI1HZ9T9T6lY0gpolVTdBuIv4oztVOrBnVQq3Zq1V7tzN3sOZxf-HYYVdo502hcRJ2VCe6fDX9Fsobi</recordid><startdate>20221125</startdate><enddate>20221125</enddate><creator>Arjun, V.</creator><creator>Muthukumaran, K.P.</creator><creator>Ramachandran, K.</creator><creator>Nithya, A.</creator><creator>Karuppuchamy, S.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20221125</creationdate><title>Fabrication of efficient and stable planar perovskite solar cell using copper oxide as hole transport material</title><author>Arjun, V. ; Muthukumaran, K.P. ; Ramachandran, K. ; Nithya, A. ; Karuppuchamy, S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c337t-fd7ab11de57ce95b584bcc58f76a911764d1dfd20e3f39a10d4ac335c3c9870f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Copper oxide</topic><topic>Copper oxides</topic><topic>Efficiency</topic><topic>Electron recombination</topic><topic>Energy conversion efficiency</topic><topic>Hole transport material</topic><topic>Metal oxides</topic><topic>Nanoparticles</topic><topic>Organometallic planar perovskite solar cells</topic><topic>Perovskites</topic><topic>Photoelectric effect</topic><topic>Photovoltaic cells</topic><topic>Production costs</topic><topic>Solar cells</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Arjun, V.</creatorcontrib><creatorcontrib>Muthukumaran, K.P.</creatorcontrib><creatorcontrib>Ramachandran, K.</creatorcontrib><creatorcontrib>Nithya, A.</creatorcontrib><creatorcontrib>Karuppuchamy, S.</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of alloys and compounds</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arjun, V.</au><au>Muthukumaran, K.P.</au><au>Ramachandran, K.</au><au>Nithya, A.</au><au>Karuppuchamy, S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of efficient and stable planar perovskite solar cell using copper oxide as hole transport material</atitle><jtitle>Journal of alloys and compounds</jtitle><date>2022-11-25</date><risdate>2022</risdate><volume>923</volume><spage>166285</spage><pages>166285-</pages><artnum>166285</artnum><issn>0925-8388</issn><eissn>1873-4669</eissn><abstract>Hole transport material (HTM) is an important component for fabricating the organometallic planar perovskite solar cells (OPSC). Metal oxide based hole transport materials are developed to increase the device stability and minimize the fabrication cost. In this article, the CuO nanoparticles (NPs) is prepared by precipitation, microwave and hydrothermal assisted methods and used as hole transport material for planar OPSCs. The hydrothermally prepared CuO (H-CuO) has highest power conversion efficiency (PCE) among the other devices. The power conversion efficiency is increased in the order of P-CuO< M-CuO< H-CuO. The maximum photocurrent of 16.98 mA/cm2, power conversion efficiency of 7.75% and 960 h of stability was achieved with H-CuO based devices. The synthesized CuO NPs make good interfacial contact between perovskite and carbon electrode and exhibit better device performance. Experimental studies revealed that the CuO NPs acts as a HTM, which enhances the charge extraction and effectively suppresses the electron recombination in the OPSC. CuO NPs based OPSC shows good device stability as compared to P3HT based devices.
•Hole Transport Material (HTM) has been prepared for fabricating perovskite solar cells.•CuO nanoparticles used as a HTM which is prepared by solution growth techniques.•Optical, structural, morphological and elemental analyses were carried out.•CuO NPs have good interfacial contact between perovskite and carbon electrode.•The synthesized CuO NPs exhibit better photovoltaic performance.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.jallcom.2022.166285</doi></addata></record> |
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| subjects | Copper oxide Copper oxides Efficiency Electron recombination Energy conversion efficiency Hole transport material Metal oxides Nanoparticles Organometallic planar perovskite solar cells Perovskites Photoelectric effect Photovoltaic cells Production costs Solar cells Stability |
| title | Fabrication of efficient and stable planar perovskite solar cell using copper oxide as hole transport material |
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