A high-performance polymer hydrogel derived from konjac flying powder for removal of heavy metals

Agricultural byproducts have excellent potential for pollutant remediation due to their low-cost and environmental sustainability. Konjac flying powder (KFP) is a fine particulate byproduct of the production of konjac glucomannan, accounting for 30-40 wt% of the total raw materials. In this work, KF...

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Veröffentlicht in:New journal of chemistry 2022-10, Vol.46 (38), p.1849-18497
Hauptverfasser: Zhong, Liuyue, Li, Tingcheng, Zhang, Junheng, Chen, Shaohua, Zhang, Daohong
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Sprache:eng
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Zusammenfassung:Agricultural byproducts have excellent potential for pollutant remediation due to their low-cost and environmental sustainability. Konjac flying powder (KFP) is a fine particulate byproduct of the production of konjac glucomannan, accounting for 30-40 wt% of the total raw materials. In this work, KFP was modified by free radical grafting copolymerization with acrylic acid, methacrylic acid and N , N ′-methylene bis(acrylamide). The lightly crosslinked product demonstrated excellent adsorption performance for heavy metals, with the maximum adsorption capacity for Cd( ii ), Pb( ii ) and Cu( ii ) reaching 635 mg g −1 , 812 mg g −1 , and 855 mg g −1 , respectively, under optimized conditions. The adsorption isotherm of heavy metal ions fitted well with the Langmuir model. Moreover, the adsorption performance was nearly unchanged after several adsorption-desorption cycles, suggesting that polymeric derivation of KFP has great potential for the remediation of heavy metal pollution. Agricultural byproducts have excellent potential for pollutant remediation due to the low-cost and environmental sustainability.
ISSN:1144-0546
1369-9261
DOI:10.1039/d2nj03389e