A high-performance polymer hydrogel derived from konjac flying powder for removal of heavy metals
Agricultural byproducts have excellent potential for pollutant remediation due to their low-cost and environmental sustainability. Konjac flying powder (KFP) is a fine particulate byproduct of the production of konjac glucomannan, accounting for 30-40 wt% of the total raw materials. In this work, KF...
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Veröffentlicht in: | New journal of chemistry 2022-10, Vol.46 (38), p.1849-18497 |
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Sprache: | eng |
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Zusammenfassung: | Agricultural byproducts have excellent potential for pollutant remediation due to their low-cost and environmental sustainability. Konjac flying powder (KFP) is a fine particulate byproduct of the production of konjac glucomannan, accounting for 30-40 wt% of the total raw materials. In this work, KFP was modified by free radical grafting copolymerization with acrylic acid, methacrylic acid and
N
,
N
′-methylene bis(acrylamide). The lightly crosslinked product demonstrated excellent adsorption performance for heavy metals, with the maximum adsorption capacity for Cd(
ii
), Pb(
ii
) and Cu(
ii
) reaching 635 mg g
−1
, 812 mg g
−1
, and 855 mg g
−1
, respectively, under optimized conditions. The adsorption isotherm of heavy metal ions fitted well with the Langmuir model. Moreover, the adsorption performance was nearly unchanged after several adsorption-desorption cycles, suggesting that polymeric derivation of KFP has great potential for the remediation of heavy metal pollution.
Agricultural byproducts have excellent potential for pollutant remediation due to the low-cost and environmental sustainability. |
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ISSN: | 1144-0546 1369-9261 |
DOI: | 10.1039/d2nj03389e |