Luminescence and energy transfer of Sm3+/Eu3+ co-doped transparent glass ceramics

The Sm 3+ /Eu 3+ doped transparent glass ceramics (GCs) containing Na 7.15 (Al 7.2 Si 8.8 O 32 ) crystallite were successfully prepared by melt crystallization. Combined with differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electron microscope (SEM) and light transmittance curve, so the best heat treat condition of GCs is 560 °C for 2 h. According to the emission spectrum, the appropriate doping concentration of Sm 3+ and Eu 3+ is determined to be 0.3% and 0.7%, respectively. The decrease of fluorescence lifetime of Sm 3+ confirms the energy transfer (ET) from Sm 3+ to Eu 3+ . The critical distance between Sm 3+ and Eu 3+ is 5.15 nm, and the mechanism of ET is electric multipole interaction. The chromaticity coordinates are calculated according to the emission spectrum, and luminescence color of GCs is in red region. So the Sm 3+ /Eu 3+ co-doped containing Na 7.15 (Al 7.2 Si 8.8 O 32 ) crystallite GCs is a promising red luminescent material.