Characterization of a Half-Bent RuNO Mode on a Dinuclear Ruthenium Complex through Reduction Reaction

Characterization of a Half-Bent RuNO Mode on a Dinuclear Ruthenium Complex through Reduction Reaction

To study behavior of a NO ligand on a dinuclear complex, preparations of dinuclear complexes having a NO and an inert ligand through substitution reactions were targeted. Reduction of a CO or a tBuNC coordinated dinuclear complexes resulted in dinuclear complexes with a half-bent NO ligand.

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Veröffentlicht in:Bulletin of the Chemical Society of Japan 2022-08, Vol.95 (8), p.1214-1216
Hauptverfasser: Arikawa, Yasuhiro, Yamada, Motoki, Otsubo, Yuji, Takeuchi, Yuki, Ikeda, Ayumi, Horiuchi, Shinnosuke, Sakuda, Eri, Umakoshi, Keisuke
Format: Artikel
Sprache:eng
Schlagworte:
Chemical reduction
Ligands
Ruthenium compounds
Substitution reactions
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Beschreibung
Zusammenfassung:To study behavior of a NO ligand on a dinuclear complex, preparations of dinuclear complexes having a NO and an inert ligand through substitution reactions were targeted. Reduction of a CO or a tBuNC coordinated dinuclear complexes resulted in dinuclear complexes with a half-bent NO ligand.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20220125