SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL
A Co(II) complex with 1-{1-[2-( o -tolyloxy)ethyl]-1 H -benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L) 3 ] 2+ ·2(NO 3 ) – ·2H 2 O·2CH 3 OH. Its crystal structure is determined by single-crystal XRD....
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| Veröffentlicht in: | Journal of structural chemistry 2022-08, Vol.63 (8), p.1284-1290 |
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| container_title | Journal of structural chemistry |
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| creator | Burlov, A. S. Divaeva, L. N. Vlasenko, V. G. Koshchienko, Yu. V. V. Chaltsev, B. V. Mashchenko, S. A. Kiskin, M. A. |
| description | A Co(II) complex with 1-{1-[2-(
o
-tolyloxy)ethyl]-1
H
-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)
3
]
2+
·2(NO
3
)
–
·2H
2
O·2CH
3
OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group
P
2
1
/
c
. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN
3
O
3
corresponds to a distorted octahedron. |
| doi_str_mv | 10.1134/S0022476622080091 |
| format | Article |
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o
-tolyloxy)ethyl]-1
H
-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)
3
]
2+
·2(NO
3
)
–
·2H
2
O·2CH
3
OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group
P
2
1
/
c
. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN
3
O
3
corresponds to a distorted octahedron.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476622080091</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Cobalt compounds ; Crystal structure ; Hydroxyl groups ; Imidazole ; Infrared spectroscopy ; Inorganic Chemistry ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Single crystals ; Solid State Physics ; X-ray diffraction</subject><ispartof>Journal of structural chemistry, 2022-08, Vol.63 (8), p.1284-1290</ispartof><rights>Pleiades Publishing, Ltd. 2022</rights><rights>Pleiades Publishing, Ltd. 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-dbd8434c79159d02b3c65349f527ac00c698767f8f68ddad0e142cd2a674cd853</citedby><cites>FETCH-LOGICAL-c246t-dbd8434c79159d02b3c65349f527ac00c698767f8f68ddad0e142cd2a674cd853</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476622080091$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476622080091$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Burlov, A. S.</creatorcontrib><creatorcontrib>Divaeva, L. N.</creatorcontrib><creatorcontrib>Vlasenko, V. G.</creatorcontrib><creatorcontrib>Koshchienko, Yu. V. V.</creatorcontrib><creatorcontrib>Chaltsev, B. V.</creatorcontrib><creatorcontrib>Mashchenko, S. A.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><title>SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><description>A Co(II) complex with 1-{1-[2-(
o
-tolyloxy)ethyl]-1
H
-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)
3
]
2+
·2(NO
3
)
–
·2H
2
O·2CH
3
OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group
P
2
1
/
c
. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN
3
O
3
corresponds to a distorted octahedron.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt compounds</subject><subject>Crystal structure</subject><subject>Hydroxyl groups</subject><subject>Imidazole</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>X-ray diffraction</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhoMoOKc_wLuAN9tFNEnTJL3sus4WslXWDNeJlK4f4tB1ttuFDP-7GRO8EK_Oged5z4EXgGuCbwmx2F2MMaVMcE4plhg75AR0iC0sJIVwTkHngNGBn4OLtl1ho0iHd8A-TiY68OMwhu5kCL1pEmtXwVhPZ56eTX0YjaDh0IsGrtK9MOybdfyg_Dl8DHUACdoT9ERRr0ZQRypR0Tzp-zpI1DMiARr4k0U4DofuIlI-oihRXwa6E0RQpC7BWZW9teXVz-yC2cjXXoBUdB96rkI5ZXyLimUhmcVy4RDbKTBdWjm3LeZUNhVZjnHOHSm4qGTFZVFkBS4Jo3lBMy5YXkjb6oKb491NU3_synabrupdszYvUyqwgxljRBiLHK28qdu2Kat007y-Z81nSnB66Dj907HJ0GOmNe76pWx-L_8f-gaVD3KG</recordid><startdate>20220801</startdate><enddate>20220801</enddate><creator>Burlov, A. S.</creator><creator>Divaeva, L. N.</creator><creator>Vlasenko, V. G.</creator><creator>Koshchienko, Yu. V. V.</creator><creator>Chaltsev, B. V.</creator><creator>Mashchenko, S. A.</creator><creator>Kiskin, M. A.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20220801</creationdate><title>SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL</title><author>Burlov, A. S. ; Divaeva, L. N. ; Vlasenko, V. G. ; Koshchienko, Yu. V. V. ; Chaltsev, B. V. ; Mashchenko, S. A. ; Kiskin, M. A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-dbd8434c79159d02b3c65349f527ac00c698767f8f68ddad0e142cd2a674cd853</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt compounds</topic><topic>Crystal structure</topic><topic>Hydroxyl groups</topic><topic>Imidazole</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Burlov, A. S.</creatorcontrib><creatorcontrib>Divaeva, L. N.</creatorcontrib><creatorcontrib>Vlasenko, V. G.</creatorcontrib><creatorcontrib>Koshchienko, Yu. V. V.</creatorcontrib><creatorcontrib>Chaltsev, B. V.</creatorcontrib><creatorcontrib>Mashchenko, S. A.</creatorcontrib><creatorcontrib>Kiskin, M. A.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Burlov, A. S.</au><au>Divaeva, L. N.</au><au>Vlasenko, V. G.</au><au>Koshchienko, Yu. V. V.</au><au>Chaltsev, B. V.</au><au>Mashchenko, S. A.</au><au>Kiskin, M. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><date>2022-08-01</date><risdate>2022</risdate><volume>63</volume><issue>8</issue><spage>1284</spage><epage>1290</epage><pages>1284-1290</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>A Co(II) complex with 1-{1-[2-(
o
-tolyloxy)ethyl]-1
H
-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)
3
]
2+
·2(NO
3
)
–
·2H
2
O·2CH
3
OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group
P
2
1
/
c
. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN
3
O
3
corresponds to a distorted octahedron.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476622080091</doi><tpages>7</tpages></addata></record> |
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| subjects | Atomic Atomic/Molecular Structure and Spectra Chemical analysis Chemistry Chemistry and Materials Science Cobalt compounds Crystal structure Hydroxyl groups Imidazole Infrared spectroscopy Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid State Physics X-ray diffraction |
| title | SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL |
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