SYNTHESIS AND CRYSTAL STRUCTURE OF THE COBALT(II) COMPLEX WITH 1-{1-[2-(o- TOLYLOXY)ETHYL]-1H-BENZIMIDAZOLE-2-YL}ETHAN-1-OL
A Co(II) complex with 1-{1-[2-( o -tolyloxy)ethyl]-1 H -benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L) 3 ] 2+ ·2(NO 3 ) – ·2H 2 O·2CH 3 OH. Its crystal structure is determined by single-crystal XRD....
Gespeichert in:
Veröffentlicht in: | Journal of structural chemistry 2022-08, Vol.63 (8), p.1284-1290 |
---|---|
Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | A Co(II) complex with 1-{1-[2-(
o
-tolyloxy)ethyl]-1
H
-benzimidazol-2-yl}ethan-1-ol is prepared. It is established by elemental analysis and IR spectroscopy that the composition of the complex is [Co(L)
3
]
2+
·2(NO
3
)
–
·2H
2
O·2CH
3
OH. Its crystal structure is determined by single-crystal XRD. According to the XRD data, the complex crystallizes in the monoclinic space group
P
2
1
/
c
. In the mononuclear molecule of the complex, three chelate ligands are coordinated to the Co(II) cation by the O atoms of the hydroxyl group and the N atoms of the imidazole ring. The coordination environment of the cobalt atom CoN
3
O
3
corresponds to a distorted octahedron. |
---|---|
ISSN: | 0022-4766 1573-8779 |
DOI: | 10.1134/S0022476622080091 |