Nitronyl-nitroxide PCP-pincer complexes of palladium and nickel: synthesis and an EPR study

The possibility of the application of nitronyl-nitroxide ligand (NIT) as a spin label for the study of the composition of transition metals complexes with M-NIT bonds by EPR spectroscopy was explored using PCP-pincer complexes of Pd and Ni as examples.

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Veröffentlicht in:Russian chemical bulletin 2022-07, Vol.71 (7), p.1527-1532
Hauptverfasser: Kozhanov, K. A., Cherkasov, V. K., Bubnov, M. P.
Format: Artikel
Sprache:eng
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Zusammenfassung:The possibility of the application of nitronyl-nitroxide ligand (NIT) as a spin label for the study of the composition of transition metals complexes with M-NIT bonds by EPR spectroscopy was explored using PCP-pincer complexes of Pd and Ni as examples.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-022-3560-9