Polystyrene-Bound Hydrazone Schiff Base Molybdenum Complex: Synthesis, Characterization, and Application as a Reusable Heterogeneous Catalyst in the Oxidation of Sulfides
A dioxomolybdenum hydrazone Schiff base complex immobilized on chloromethylated polystyrene [MoO 2 L@CMP] was synthesized and characterized by various spectroscopic techniques like FT-IR, UV-Vis, DRS, SEM and EDAX. Its catalytic activity was investigated in the oxidation of various aliphatic and aro...
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Veröffentlicht in: | Russian journal of organic chemistry 2022-06, Vol.58 (6), p.850-857 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | A dioxomolybdenum hydrazone Schiff base complex immobilized on chloromethylated polystyrene [MoO
2
L@CMP] was synthesized and characterized by various spectroscopic techniques like FT-IR, UV-Vis, DRS, SEM and EDAX. Its catalytic activity was investigated in the oxidation of various aliphatic and aromatic sulfides using H
2
O
2
as an oxidant in ethanol as a green solvent under reflux conditions. The catalyst could readily be separated from the reaction mixture and reused in subsequent reactions with no significant loss of activity. |
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ISSN: | 1070-4280 1608-3393 |
DOI: | 10.1134/S1070428022060148 |