Direct conversion of isopropanol to C6+ branched compounds as high-octane gasoline blendstocks

Direct conversion of isopropanol to C6+ branched compounds as high-octane gasoline blendstocks

The development of fermentation engineering makes isopropanol derived from lignocellulose a potential biomass platform molecule. Here we report the one-pot synthesis of C6+ branched compounds from isopropanol condensation on Ni/MoC catalysts. The ideal branched-chain selectivity in C6+ and nonnecess...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2022-07, Vol.24 (13), p.5083-5087
Hauptverfasser: Zhou, Wei, Gao, Zirui, Wang, Meng, Wu, Genghuang, Rong, Junfeng, Ding, Ma
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Chain branching
Chemical synthesis
Condensates
Direct conversion
Fermentation
Gasoline
Green chemistry
Isopropanol
Lignocellulose
Octane
Selectivity
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Zusammenfassung:The development of fermentation engineering makes isopropanol derived from lignocellulose a potential biomass platform molecule. Here we report the one-pot synthesis of C6+ branched compounds from isopropanol condensation on Ni/MoC catalysts. The ideal branched-chain selectivity in C6+ and nonnecessity of H2 make this route advantageous in high-octane gasoline blendstock production.
ISSN:1463-9262
1463-9270
DOI:10.1039/d2gc01200f