Synthesis of Ethyl Ethers 13,14-Dehydro-16-aryloxy-11-deoxyprostaglandin E1
Conjugated 1,4-addition of cuprate reagents, prepared from trimethylsilyl ethers of 3-hydroxy-4-aryloxybut-1-ynes, to 2-[6-(ethoxycarbonyl)hexyl]cyclopent-2-en-1-one resulted in the preparation of 13,14-dehydro-16-aryloxy-11-deoxyprostaglandins E 1 as mixtures of the 8,12- cis/trans isomers.
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| Veröffentlicht in: | Russian journal of organic chemistry 2022, Vol.58 (5), p.691-696 |
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| container_title | Russian journal of organic chemistry |
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| creator | Ivanova, N. A. Shavaleeva, G. A. Miftakhov, M. S. |
| description | Conjugated 1,4-addition of cuprate reagents, prepared from trimethylsilyl ethers of 3-hydroxy-4-aryloxybut-1-ynes, to 2-[6-(ethoxycarbonyl)hexyl]cyclopent-2-en-1-one resulted in the preparation of 13,14-dehydro-16-aryloxy-11-deoxyprostaglandins E
1
as mixtures of the 8,12-
cis/trans
isomers. |
| doi_str_mv | 10.1134/S1070428022050086 |
| format | Article |
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as mixtures of the 8,12-
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| ispartof | Russian journal of organic chemistry, 2022, Vol.58 (5), p.691-696 |
| issn | 1070-4280 1608-3393 |
| language | eng |
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| subjects | Chemistry Chemistry and Materials Science Ethers Organic Chemistry Reagents |
| title | Synthesis of Ethyl Ethers 13,14-Dehydro-16-aryloxy-11-deoxyprostaglandin E1 |
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