Iminyl radical-triggered relay annulation for the construction of bridged aza-tetracycles bearing four contiguous stereogenic centers

Bridged tetracyclic nitrogen scaffolds are found in numerous biologically active molecules and medicinally relevant structures. Traditional methods usually require tedious reaction steps, and/or the use of structurally specific starting materials. We report an unprecedented, iminyl radical-triggered...

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Veröffentlicht in:Chemical science (Cambridge) 2022-06, Vol.13 (24), p.7283-7288
Hauptverfasser: Jiang, Kun, Li, Shi-Jun, Liu, Qing-Peng, Yu, Ning, Li, Yu-Lin, Zhou, Yu-Qiang, He, Kui-Cheng, Lin, Jing, Zheng, Ting-Yu, Lang, Jian, Lan, Yu, Wei, Ye
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Sprache:eng
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