Development and greenness evaluation of solid-phase extraction and salting-out liquid–liquid extraction method for determination of herbicides in water, soil and rice

Solid-phase extraction (SPE) and salting-out-assisted liquid–liquid extraction (SALLE) method was optimized and validated for the extraction and quantification of anilofos, bispyribac sodium, butachlor, pendimethalin, pretilachlor and penoxsulam from environmental water, soil and rice samples using HPLC and LC–MS/MS. The limit of detection and limit of quantification ranged from 0.0026 to 0.03 and 0.008 to 0.09 μg mL −1 in different matrices using HPLC and LC–MS/MS. Under the optimal conditions, mean percent recoveries ranged from 81.6 ± 4.1 to 98.6 ± 3.5, 84.1 ± 3.5 to 99.4 ± 3.2 and 81.3 ± 4.2 to 94.6 ± 3.5 in water, soil and rice, respectively, using SPE while 84.9 ± 2.9 to 102.3 ± 2.3, 90.0 ± 4.1 to 103.2 ± 4.1 and 86.3 ± 2.7 to 94.6 ± 3.5 using SALLE. Acceptable recoveries (> 80%) and precision (