Versatile Synthesis of Mesoporous Crystalline TiO2 Materials by Monomicelle Assembly

Mesoscale TiO2 structures have realized many technological applications—ranging from catalysis and biomedicine to energy storage and conversion—because of their large mesoporosities offering desirable accessibility and mass transport. Tailoring mesoporous TiO2 structures with novel mesoscopic and microscopic configurations is envisaged to offer ample opportunities for further applications. In this Review, we explain how to synthesize novel mesoporous TiO2 materials and present recent examples. An emphasis is placed on a “monomicelle assembly” strategy as an emerging and powerful approach to direct the formation of mesostructured TiO2 with precise control over its structural orientations and architectures. Furthermore, typical examples of mesoporous TiO2 for applications in batteries and photocatalysis are highlighted. The Review ends with an outlook towards the synthesis of mesoporous TiO2 with tailored architectures by self‐assembly, which could pave the way for developing advanced energy conversion and storage devices. Tailoring mesoporous TiO2 at the mesoscopic and microscopic level has been advancing in the last decade as its unique nanoscale architectures are of great importance for various applications. This Review surveys and discusses how to synthesize a series of novel mesoporous TiO2 materials, with the aim of highlighting how precise control can be achieved over the mesostructure and also potential synthetic directions.